SILICA-RICH WASTE TO SUSTAINABLE NANOFIBERS VIA ELECTROSPINNING: A SYSTEMATIC REVIEW
DOI:
https://doi.org/10.53067/ijomral.v4i5.368Keywords:
silica-rich waste, nanofiber, electrospinning, circular economy, sustainable materials, systematic reviewAbstract
Often overlooked in conventional waste management systems, silica-rich waste holds untapped potential as a sustainable precursor for advanced nanomaterials. This systematic review critically examines how diverse industrial and agricultural silica-rich residues such as rice husk ash, glass waste, and geothermal sludge can be valorized into functional nanofibers via electrospinning. Applying the PRISMA framework, 150 peer-reviewed studies (2014–2024) were synthesized to map current research on waste selection, silica extraction methods, electrospinning parameters, and end-use performance. The review highlights that tailored purification routes can yield high-purity silica suitable for stable, defect-free nanofibers. Electrospinning success hinges on a fine-tuned interplay of solution properties, operational settings, and ambient conditions. Resulting nanofibers demonstrate outstanding performance in air/water filtration, biomedical scaffolding, and energy storage systems. However, raw material variability, process reproducibility, and scale-up potential persist. By integrating material science with circular economy principles, this work positions waste-derived nanofibers as a strategic pathway toward greener, high-value applications in resource-constrained settings.
Downloads
References
Abdel Hamid, E. M., Ismail, M., Moussa, M., Abdel Aziz, M., Sobhy, M., Mohamed, R., & Mohamed, Y. (2023). Optimization and characterization of bio-silica extraction from rice straw using RSM. Egyptian Journal of Chemistry. 66(11). 373-383.
Al-Husaini, I.S., Lau, W.J., Yusoff, A.R.M., Al-Abri, M.Z., & Al Farsi, B.A. (2021). Synthesis of functional hydrophilic polyethersulfone-based electrospun nanofibrous membranes for water treatment. Journal of Environmental Chemical Engineering. Vol 1. 104728.
Anggara, F., Besari, D. A. A., Timotius, D., Amijaya, D. H., Al Hasunah, W., Andriani, A., and Fahrialam, A. 2024. Understanding FABA composition in coal-fired power plants: Impact of operating conditions and combustion efficiency on ash characteristics–A case study in PT Bukit Asam, South Sumatra, Indonesia. Results in Engineering. 23.102590.
Cheng, D., Li, Y., Zhang, J., Tian, M., Wang, B., He, Z., & Wang, L. (2020). Recent electrospun carbon fiber electrode advances for vanadium redox flow battery: properties, structures, and perspectives. Carbon. 170. 527–542.
Cui, J., Li, F., Wang, Y., Zhang, Q., Ma, W., & Huang, C. (2020). Electrospun nanofiber membranes for wastewater treatment applications. Separation and Purification Technology. 250. 117116.
Cui, J., Lu, T., Li, F., Wang, Y., Lei, J., Ma, W., & Huang, C. (2021). The flexible and transparent composite nanofibre membrane was fabricated via a “green” electrospinning method for efficient particulate matter 2.5 capture. Journal of Colloid and Interface Science. Vol 582. 506–514.
De Almeida, D.S., Martins, L.D., Muniz, E.C., Rudke, A.P., Squizzato, R., Beal, A., & Gimenes, M.L. (2020). Biodegradable CA/CPB electrospun nanofibers for efficient retention of airborne nanoparticles. Process Safety and Environmental Protection. Vol 144. 177–185.
De Oliveira, A. M., dos Reis Ferreira, R. A., and Martins Filho, P. C. 2020. Production of silica gel from waste metal silica residue. Materials Letters. 275. 128125.
Dhmees, A. S., Rashad, A. M., Eliwa, A. A., & Zawrah, M. F. (2019). Preparation and characterization of nano SiO2@ CeO2 extracted from blast furnace slag and uranium extraction waste for wastewater treatment. Ceramics International. 45(6). 7309-7317.
Figen, A.K. (2020). History, basics, and parameters of the electrospinning technique. Electrospun Materials and Their Allied Applications. 53–69.
Gavande, V., Nagappan, S., Seo, B., & Lee, W.K. (2024). A systematic review on green and natural polymeric nanofibers for biomedical applications. International Journal of Biological Macromolecules. Vol 262. 130135.
G. Anusiya & R. Jaiganesh. (2022). A review on fabrication methods of nanofibers and a special focus on the application of cellulose nanofibers. Carbohydrate Polymer Technologies and Applications. Vol 4. 100262.
Han, X., Wang, Y., Zhang, N., Meng, J., Li, Y., & Liang, J. (2021). Facile synthesis of mesoporous silica derived from iron ore tailings for efficient adsorption of methylene blue. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 617. 126391.
Hendronursito, Y., Amin, M., Sumardi, S., Marjunus, R., Clarasati, F., Birawidha, D. C., and Isnugroho, K. 2020. Granite quarry solid waste is processed into industrial high silica materials using the leaching process with HCl concentration variation. Jurnal Riset Teknologi Pencegahan Pencemaran Industri. 11(2). 43-50.
HSN, M. I., Panatarani, C., Faizal, F., Mulyana, C., & Joni, I. M. (2023). Synthesis of mesoporous Silica SBA-15 from geothermal sludge. Materialia. 27. 101637.
Li,Y., Li,Q., and Tan,Z. 2019. A review of electrospun nanofiber-based separators for rechargeable lithium-ion batteries. Journal of Power Sources. 443. 227262.
Li, Y., Li, S., Pan, X., Zhao, X., Guo, P., & Zhao, Z. (2023). Recovery and preparation of high-grade silica from iron ore tailings by S-HGMS coupling with acid leaching technology: description of separation mechanism and leaching kinetics. Powder Technology. 424. 118523.
Liu, Y., Chen, Z., Ni, H., Liu, K., & He, J. (2024). High-temperature properties of fly ash and silica fume composite magnesium potassium phosphate cement. Construction and Building Materials. 441. 137487.
Long, H., Zhu, D., Pan, J., Li, S., Guo, Z., & Xu, X. (2024). Innovative process for extracting 99.99% high-purity quartz from high-silicon iron ore tailings. Journal of Materials Research and Technology. 31. 2094-2102.
Mori, H. (2003). Extraction of silicon dioxide from waste colored glasses by alkali fusion using potassium hydroxide. Journal of Materials Science. 38(16). 3461-3468.
Natrayan, L., Merneedi, A., Bharathiraja, G., Kaliappan, S., Veeman, D., & Murugan, P. (2021). Processing and characterization of carbon nanofibre composites for automotive applications. Journal of Nanomaterials. Vol 1. 7323885.
Nun, S.K., Rama, K.S., Dirisala, V.R., and Chavali, M.Y. 2017. Electrospinning of collagen nanofiber scaffolds for tissue repair and regeneration. In Nanostructures for novel therapy.
Nzereogu, P. U., Omah, A. D., Ezema, F. I., Iwuoha, E. I., and Nwanya, A. C. 2023. Silica extraction from rice husk: Comprehensive review and applications. Hybrid Advances. 4. 100111.
Olivia, M., Maulidi, M. A., & Wibisono, G. (2024). Characteristics of palm oil fuel ash concrete admixed with precipitated silica and silica fume. Cleaner Engineering and Technology. 19. 100738.
Owoeye, S. S., Jegede, F. I., and Borisade, S. G. 2020. Prepare and characterize nano-sized silica xerogel particles using sodium silicate solution extracted from waste container glasses. Materials Chemistry and Physics. 248. 122915.
Rangaraj, S., & Venkatachalam, R. (2017). A lucrative chemical processing of bamboo leaf biomass to synthesize biocompatible amorphous silica nanoparticles of biomedical importance. Applied Nanoscience. 7(5).145-153.
Rosenberger, A.G., Dragnunski, D.C., Muniz, E.C., Modenes, A.N., Alves, H.J., TARLEY, C.R.T., & Caetano, J. (2020). Electrospinning in the preparation of an electrochemical sensor based on carbon nanotubes. Journal of Molecular Liquids. 298. 112068.
Rovani, S., Santos, J. J., Corio, P., & Fungaro, D. A. (2018). Highly pure silica nanoparticles with high adsorption capacity were obtained from sugarcane waste ash. ACS omega. 3(3). 2618-2627.
Saif, S., Mubin, S., Abbass, W., Aslam, F., & Alyousef, R. (2024). Utilizing machine learning to integrate silica-based production waste material in ceramic tiles manufacturing: progressing toward sustainable solutions. Ceramics International. 50(11). 18880-18906.
Seggiani, M., & Vitolo, S. 2003. Recovery of silica gel from blast furnace slag. Resources, conservation, and recycling. 40(1). 71-80.
Singh, B., Kemell, M., Yliniemi, J., & Repo, T. (2024). Mesoporous silica–amine beads from blast furnace slag for CO 2 capture applications. Nanoscale. 16(34). 16251-16259.
Staples, M., & Niazi, M. (2007). Experiences using systematic review guidelines. Journal of Systems and Software. 80. 1425–1437.
Wang, M., & Liu, X. (2021). Applications of red mud as an environmental remediation material: A review. Journal of Hazardous Materials. 408. 124420.
Zhang, Y., & Ling, T. C. (2020). Reactivity activation of waste coal gangue and its impact on the properties of cement-based materials–A review. Construction and Building Materials. 234. 117424.
Zhang, A., Yang, X., Li, C., Li, Y., Chen, Y., Pan, X., and Li, S. 2024. Resource Utilization of Iron Ore Tailings to Recover SiO2 Sand Through S-HGMS: Parametric Optimization and Mechanism Analysis. JOM. 76(5). 2392-2402.
Zhao, J., Ni, K., Su, Y., and Shi, Y. 2021. An evaluation of iron ore tailings characteristics and iron ore tailings concrete properties. Construction and Building Materials. 286. 122968.
Zhao, Y., Yan, J., Yu, J., & Ding, B. (2023). Electrospun Nanofiber Electrodes for Lithium-Ion Batteries. Macromolecular Rapid Communications. Vol 44. 2200740.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2025 Louis Lumbanraja, Syafriadi

This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.











